Iron Out
Iron Out comes in either a spray or powder.
Can be found at most places and in at least my experience (when we also had a failing water softener) took care of the stains in short order. Especially designed for Iron stains and works fast. If the stains are on the bottom - cover drain fill with water a few inches and add powder - let sit for 15-30 minutes... If not and on the walls use the spray.
Would be surprised if you did not see immediate results - no scrubbing needed.
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